91桃色

Natural sunlight consists of 5% UV (300-400 nm), 43% visible (400-700 nm), and 52% infrared (700-2500 nm) [1]. When light falls onto fabric, a small portion of the light beam is absorbed rather than to be reflected or transmitted. If a light wave strikes a material with electrons having the same vibrational frequencies, then those electrons will absorb the energy of the light wave and transform it into vibrational motion and the electrons interact with neighbouring atoms and convert its vibrational energy into thermal energy. Subsequently, the light wave with that given frequency is absorbed by the object and never reverse in the form of light. To give a silvery and shiny lustre to the substrate, aluminium pigments are commonly used in coatings under the slightly alkaline conditions of most waterborne paints, aluminium reacts with water and forms aluminium oxide and aluminium hydroxide. This reaction process leads a big problem because there is a loss of the metallic appearance of the pigment particles. Surface modification of aluminium is necessary to avoid reaction and to be protected from water [2]. The introduction of hydroxyl groups would be expected to lead to a surface with a stronger interaction with water [3].

Different optical properties such as absorption, transmission, and reflection properties of the fabrics are determined primarily by the constructional parameters of textiles [4,5]. But these properties can be influenced when the textile surface is modified by different nanoparticles. Levinson suggested optical properties of a freely suspended film (i.e., reflectance, transmittance, and absorptance) depend on three factors such as refractive indices of the pigment and the binder, the construction and concentration of the pigment nanoparticles and obviously the thickness of coated film [6]. Of course, according to the transmission line theory, the performance of a microwave absorption material mainly depends on the intrinsic electrical conductivity, dielectric constant and magnetic permeability [7]. Traditional coloured paints absorb the majority of the incoming solar radiation. An exception has been found for lightly coloured whitish paints [8]. A cool coating must have two criteria: low visible transmittance and low NIR absorptance to minimize NIR heat gain.

Textile modification with nanoparticle provides desirable effects on applied surface without alteration of the fiber’s basic properties. A lot of experiments were conducted based on surface treatment to achieve different developed properties. Experiments are conducted basically on Ti, Ag, Cu, Zn, and other transition metals. At present, research of TiO₂ treated textile goes largely on UV protection, antimicrobial, and selfcleaning properties. Depletion of the ozone layer causes TiO₂ modified textile to be particularly important for the textile industry because of its UV protection property. TiO₂ provides desirable protection when it refracts and/scatters the most UV rays through a high refractive index by absorbing UV rays [9]. Silver improves the performance of TiO₂ photocatalyst as it reduces the electron-hole recombination rate and by extending the range of light absorbed by TiO₂ to visible region [10,11]. TiO₂ rutile is a strongly scattering and weakly absorbing pigment. Titanium dioxide white scatters strongly in most of the solar spectrum but absorbs strongly in the UV (below 400 nm). There is little absorption in most of the visible and infrared spectra [1].

To improve its efficiency is to shift its absorption from the UV region into the visible-light region which allows more photons to be absorbed [12]. One of the most limitations of TiO₂ nanoparticle is high rate of electron-hole recombination. So, one way is doping TiO₂ with B, P or F atoms by the sol-gel method [13-18]. By adding various dopants into its lattice, much progress has been found in the area of visible light-active TiO₂, including metal [19-21] and nonmetal elements [22-26]. Chen et al. examined the Visible-Light Absorption Properties of C-, N- and S-Doped TiO₂ Nanomaterials and found that all those doped TiO₂ nanomaterials show a yellow to light yellow color, suggesting their ability to absorb light in the visible region [12]. Mica flakes coated with titanium dioxide and iron oxide are in most cases similar to mica flakes coated with only titanium dioxide, but are more absorbing, less scattering, darker, and somewhat less reflecting in the NIR [27].

Another possibility to modify substrate surface with TiO₂ is to investigate in a combination with Ag to achieve desired antimicrobial, UV protective, and photocatalytic characteristics [28-36]. The hybrid functionalization of cotton and viscose fabrics using silver nanowires (AgNWs) colloid and TiO₂ was investigated by Giesz et al. [37]. The intercalation of AgNR arrays into the P3HT/PCBM polymer films improved the optical absorption of the films [38]. Low solar absorptance in visible and IR region has been examined with flakes of metal coated with a single or double layer of Fe₂O₃ on SiO₂ under 200 nm layer thickness [39]. Zinc oxide has been used as a white pigment for its absorbance property to light especially UV light [40]. Levinson et al. showed that zinc oxide had an absorption point at approximately 380 nm which means bellow 380 nm it has absorption property to make it opaque [6]. Iron oxide browns exhibit strong absorption in part of the visible spectrum and low absorption in the NIR. But possibly no experiment was conducted on TiO₂, in combination with aluminium pigment yet as aluminium pigment doesn’t show antimicrobial, self-cleaning or photocatalytic property which is the most demandable at present. That could one reason why researchers are not interested to work with aluminium pigment. They have another alternative like the compound of Ag, Cu, Zn, Fe or Ti. In this work, we will show the developed absorption functionalization of aluminium and TiO₂ modified aluminium effect pigment coated textile in a row.

Materials

In the experiments, both cotton and polyester textiles were used. Textiles were coated with different pigment concentrations for two different basecoats: basecoat1, without TiO₂ nanoparticles and basecoat2 with TiO₂ nanoparticles. Eckart white aluminium pigments shinedecor 3500 and shinedecor 5000 were used as metal effect pigments to achieve not only excellent whiteness color but also developed absorbed property of textiles. 30% Helizarin White RTU was added as a source of the TiO₂ nanoparticle. Following recipes are followed during metal effect coating preparation process. Two topcoats were prepared by using the bellow recipe (Table 1, Figure 1).

Table 1: Recipe of basecoat 1, basecoat 2 and topcoat

Figure 1: Layer construction.

Layer construction

Sixteen samples, eight for cotton and eight for polyester, have been treated with two aluminium effect pigments named Shinedecor 5000 and Shinedecor 5000. The samples have been ordered as bellow (Figure
2 and Table 2).

Table 2: Details of different pigment-coated textile samples

Figure 2: Absorption% of (a) Shinedecor 5000 and (b) Shinedecor 3500 effect pigment coated cotton textile treated with 2.5% and 10% pigment on topcoat and with/ without TiO₂ nanoparticle on basecoat.

Methods

Samples are placed on a strand and coated with the previously prepared solutions. The coating was done with a roller following conventional coating procedure. Fabrics were then cured at a 120- degree temperature and after curing for 2 minutes, they are then kept for 24 hours in open air for perfect penetration of the coated particles. It has been done to condense and to fix the chemical compounds on the textile substrate. The strengthened thin film was created by this way which will affect the surface property of employed property.

A UV-VIS Spectrophotometer (model: UV-2600/2700 from Shimadzu), capable of measurement wavelength up to 1400 nm, was used to measure the reflection and transmission

Firstly, the reference cotton and polyester samples were investigated to get reflection% and transmission%. Secondly, aluminium pigment coated cotton and polyester samples (having either basecoat1 or basecoat2) were examined. The sum of the reflection and the transmission% was subtracted from 100% to get absorption% of aluminium effect pigment coated textile.

Figure 2a and 1b show absorption% of aluminium effect pigment coated cotton textiles. They contain 2.5% and 10% pigment concentrations, having two different basecoats: basecoat1 (without TiO₂ nanoparticles) and basecoat2 (with TiO₂ nanoparticles). Figure 2a is for shinedecor 5000 pigment and Figure 2b is for shinedecor 3500 pigment. On the other hand, Figure 3a and 3b show the polyester samples coated with the same metal effect pigments. They include the same sample procedure in composites stated in Figure 2a and 2b.

Figure 3: Absorption% of (a) Shinedecor 5000 and (b) Shinedecor 3500 effect pigment coated polyester textile treated with 2.5% and 10% pigment on topcoat and with/ without TiO₂ nanoparticle on basecoat.

Untreated cotton textile exhibits negative charge due to the presence of hydroxyl (-OH) group at its polymer chain like other cellulosic fibre. On the other hand, polyester textile shows negative charge. It is attributed to the presence of carboxyl (-COOH) end groups. In both cases, these strong negative charges help the fibre to make strong bonding in solution stages, although polyester shows normally hydrophobic and inert nature as very little number of polar groups.

In our experiment, two different aluminium pigments were used. This metal effect pigment consists of metal platelet. This platelet helps textile to achieve both shiny silvery colour and good light scattering property as well. In the UVC region (100 nm-280 nm), the coated textiles absorb about 80-90% of light. The absorption% of untreated reference textile was about 60-70%. The phenomenon was found in both cotton (Figure 2a and 2b) and polyester (Figure 3a and 3b) samples. In the UVB and UVA region, the absorption% was decreased dramatically to 50-20% (Figure 2a and 2b) and 30-10% (Figure 3a and 3b). The coated textiles with the basecoat TiO₂ show relatively higher value of absorption% in figures 2 and 3 in the visual and IR region. In the visual and IR spectrum, all of metal effect coated samples exhibit higher absorption% in comparison with uncoated reference cotton and polyester samples.

Some researchers like Holmberg et al. showed relatively higher value of absorption% Silicon and Germanium Nanowire Fabric in visual spectrum [41]. In UV and IR regions, the results were same. But considering the textile were able property, it is very important to keep the textile cool. It is big challenge for the researchers to combine high absorption property of the coated textile in both UV and IR regions. We think that more works have to be done on this area. At all, the significance of this work is to keep the coated textile in a moderate cool condition especially in visual and IR regions.

The phenomenon of absorbing more degree of light can be analysed by the SEM image analysis. The aluminium platelets are trapped on textile surface during coating process. They are fixed permanently after the curing process. (Figures 3a-3h) for cotton and (Figure 4a-4h) for polyester show different corn-like platelets on their surfaces. The density of their appearance usually depends on the pigment concentration. If the pigment concentration is higher, the possibility of their appearance on surface is higher. Sometimes, different phenomenon has been found because of uneven distribution of pigment particles. Probably, for this reason (Figures 3b and 3e, and Figure 4a and 4b) present relatively lower amount of pigment particle than the amount to be expected. Aluminium platelets are visualized on textile surfaces by the SEM images. These platelets not only reflect the incident light but also a big amount of incident light is absorbed. In addition, TiO₂ nanoparticles also have influence on optical protection of the textile surfaces as it also scatters the incident radiation. The textile surface was treated with TiO₂ nanoparticle in combination with aluminium pigment. It showed a higher light absorption% of the coated substrate. Using TiO₂ as basecoat increases the absorbency at higher extent (Figures 4 and 5).

Figure 4: SEM images of aluminium effect pigment coated cotton ( (a) to (h)) and untreated reference cotton (i).

Figure 5: SEM images of aluminium effect pigment coated polyester ( (a) to (h)) and untreated reference polyester (i).

The higher absorption of light has been achieved by using aluminium effect pigment in along with TiO₂ or without TiO₂. In UV region, specially UVC and UVB region, this metal effect coated film gives fabric UV absorbing property. In UVC spectrum region, about 80-90% of spectrum has been absorbed which is tremendously higher. It also shows that developed absorption is parallel in visual and IR region for all the pigment coated textile and the absorption percentage is low. In NIR region, when a pigment absorbs less, the coating layer remains cool. More research on it can be possible solution to use this coated fabric as good absorber.

We would like to thank Thomas Heistermann and Dr. Thomas Grethe, Hochschule Niederrhein, for supplying the chemicals, technical help and ensuring the use of analytical instrument.